Authors
Adam Riese, Dustin Banham, Siyu Ye, Xueliang Sun
Publication date
2015/4/30
Journal
Journal of The Electrochemical Society
Volume
162
Issue
7
Pages
F783
Publisher
IOP Publishing
Description
Durability is one of the key remaining challenges to widespread adoption of proton exchange membrane fuel cells (PEMFCs). The durability and continued high performance of a PEMFC using carbon supported catalysts is highly dependent on the stability of the carbon support. Presently, there are a multitude of accelerated stress test (AST) protocols using rotating disk electrode (RDE) voltammetry to study the corrosion of carbon catalyst support materials, though it remains unclear whether all of these tests provide meaningful reproduction of in-situ membrane electrode assembly (MEA) test results. We evaluate two carbon corrosion ASTs and compare results to MEA data for three well known carbon supported catalysts. Physical characterization of each carbon type by gas sorption, XRD, and Raman, is used to elucidate the observed trends in corrosion resistance and the effects of testing temperature, scan rate …
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