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The development of low‐cost printed organic electronics entails the processing of active organic semiconductors (OSCs) through solution‐based techniques. However, the preparation of large‐area uniform and reproducible films based on OSC inks can be very challenging due to the low viscosity of their solutions, which causes dewetting problems, the low stability of OSC polymer solutions, or the difficulty in achieving appropriate crystal order. To circumvent this, a promising route is the use of blends of OSCs and insulating binding polymers. This approach typically gives rise to films with an enhanced crystallinity and organic field‐effect transistors (OFETs) with significantly improved device performance. Recent progress in the fabrication of OFETs based on OSC/binding polymer inks is reviewed, highlighting the main morphological and structural features that play a major role in determining the final electrical …