Authors
S Bandow, G Chen, GU Sumanasekera, R Gupta, M Yudasaka, S Iijima, PC Eklund
Publication date
2002/8/26
Journal
Physical Review B
Volume
66
Issue
7
Pages
075416
Publisher
American Physical Society
Description
Double-wall carbon nanotubes (DWNT’s) have been studied by Raman scattering using different excitation wavelengths and their spectra compared to those of single wall nanotubes (SWNT’s) and C 60-SWNT peapods. Raman scattering from the radial and tangential vibrational modes of very small diameter d∼ 0.6–0.9 nm secondary (interior) semiconducting tubes within the DWNT can be unambiguously identified with 647.1 and 1064 nm excitations. The frequency of the tangential displacement vibrational modes identified with these secondary (interior) tubes is found to be downshifted by∼ 7 cm− 1 relative to that of the larger primary (exterior) tubes that exhibit a diameter d∼ 1.3–1.6 nm. This downshift strongly suggests that at small tube diameters (ie, d∼ 0.7 nm), the associated wall curvature of the nanotube may require an admixture of sp 3 character in the CC interaction. Our results also show that the value …
Total citations
Scholar articles
S Bandow, G Chen, GU Sumanasekera, R Gupta… - Physical Review B, 2002