Authors
Gugang Chen, S Bandow, ER Margine, C Nisoli, AN Kolmogorov, Vincent H Crespi, R Gupta, GU Sumanasekera, S Iijima, PC Eklund
Publication date
2003/6/27
Journal
Physical Review Letters
Volume
90
Issue
25
Pages
257403
Publisher
American Physical Society
Description
A double-walled carbon nanotube is used to study the radial charge distribution on the positive inner electrode of a cylindrical molecular capacitor. The outer electrode is a shell of bromine anions. Resonant Raman scattering from phonons on each carbon shell reveals the radial charge distribution. A self-consistent tight-binding model confirms the observed molecular Faraday cage effect, i.e., most of the charge resides on the outer wall, even when this wall was originally semiconducting and the inner wall was metallic.
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