Authors
Qiqi Zhang, Seid Yimer Abate, Guorong Ma, Yifang Qi, Jada Emodogo, Kira Williams, Shafi Muhammad, Zhongliang Ouyang, Paresh Chandra Ray, Glake Hill, Xiaodan Gu, Dawen Li, Qilin Dai
Publication date
2023/11/28
Journal
ACS Applied Electronic Materials
Volume
5
Issue
12
Pages
6874-6883
Publisher
American Chemical Society
Description
Solution processable perovskite solar cells (PSCs) are one of the most promising candidates for commercialization. However, the perovskite film preparation method is limited by the mandatory antisolvent process under an inert gas atmosphere which significantly influenced its mass production. In this study, we developed a perovskite film preparation without the requirement of antisolvent dripping in air. We employed various solvents to prepare perovskite films and studied their influence on perovskite nucleation and morphology for the respective solvents. Among them, the perovskite prepared using dimethylacetamide (DMAc), which has low solubility and high interaction with PbI2, demonstrated a highly crystalline perovskite black phase without antisolvent dripping. Furthermore, we found that the perovskite concentration played an important role in the perovskite film quality, where the high concentration DMAc …
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