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Augmented reality (AR) integrates virtual information into a learner’s physical environment, so that the learner will perceive that information as existing in the environment. Many augmented reality applications were quite successful in previous educational environments. This study attempts to build a prototype of augmented reality learning system for health care and to enable learners to make use of extensive interactions with the system and real world. After that, this study is evaluated by the learners’ motivation and intention to use the AR learning system. The results showed that immersion and interactivity features were two predictors for learners’ motivation. Furthermore, learners’ motivation is the most important factor to affect learner’s behavioral intention to use an AR learning system.