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Ultraviolet B (UVB) rays vary with time and season and are the major cause of sunburns. Sunburned skin is a leading risk factor for melanoma and non-melanoma skin cancers. Protection against exposure to UVB rays may be achieved by a combination of various approaches such as use of broad spectrum sunscreen formulations. UV radiations (UVR) absorbed by the skin surface can produce harmful compounds called free radicals or reactive oxygen species (ROS), which can cause skin cancer and premature aging. To reduce ROS generation and damage, researchers recommend using sunscreen to protect the skin from harmful UVR. The realm of possibilities in photoprotection may include the development of sunscreens which remain at the surface of the skin for a longer time and may incorporate antioxidants that can neutralize ROS. By quenching free radicals, antioxidants may aid photoprotection effect. This review focuses on photoprotection from UVB radiation and discusses potential herbal candidates with antioxidant properties that can serve as a strong barrier in cosmeceuticals to protect skin against harmful UVB rays.