Authors
Cheng Liu, Zheng Luo, Wentao Deng, Weifeng Wei, Libao Chen, Anqiang Pan, Jianmin Ma, Chiwei Wang, Limin Zhu, Lingling Xie, Xiao-Yu Cao, Jiugang Hu, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji
Publication date
2021/1/26
Journal
ACS Energy Letters
Volume
6
Issue
2
Pages
675-683
Publisher
American Chemical Society
Description
Ameliorating the interfacial issues of the zinc anode, particularly dendrite growth and electrode corrosion, is imperative for rechargeable zinc metal batteries. Herein, an electrochemical-inert liquid gallium–indium alloy coating is designed toward the zinc anode, inspired by the gallium–indium–zinc phase diagram. This unique liquid coating prefers an inward-deposition of Zn underneath the liquid coating assisted by ultrafast mass/charge transport when charging. Moreover, the corrosion of the modified zinc anode is improved as well, depiciting a hydrogen-evolution reaction overpotential higher than that of the reference zinc anode. Consequently, it enables a polarization of 24 mV, the lowest to the best of our knowledge, at 0.25 mA cm–2 with a prolonged lifespan (2100 h), which further enables the corresponding MnO2 full cells with improved capacity retention and stage of charge above 96% after 48 h. This …
Total citations
20212022202320249456443
Scholar articles
C Liu, Z Luo, W Deng, W Wei, L Chen, A Pan, J Ma… - ACS Energy Letters, 2021