Authors
Jun He, Rajasekhar Balasubramanian
Publication date
2009/9/1
Journal
Atmospheric Environment
Volume
43
Issue
29
Pages
4375-4383
Publisher
Pergamon
Description
Gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were collected at a tropical site in Southeast Asia over 12-h periods during November and December 2006 to determine their gas/particle distributions by analyzing integrated quartz filter and polyurethane foam samples. Gas/particle partitioning coefficients, Kp, were calculated, and their relationship with the subcooled liquid vapor pressure pLo for both PAHs and PCBs was investigated. The regressions of log Kp vs. log pLo for most of samples gave high correlations for both PAHs and PCBs and the slopes were statistically shallower than −1, but they were relatively steeper than those obtained in temperate zones of the Northern Hemisphere. By comparison, the particle-bound fraction of low molecular weight (LMW) PAHs was underestimated by both Junge-Pankow adsorption and KOA (octanol–air partition …
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