Authors
Jorge A Campos-Gonzalez-Angulo, Joel Yuen-Zhou
Publication date
2020/4/30
Journal
The Journal of chemical physics
Volume
152
Issue
16
Publisher
AIP Publishing
Description
A series of experiments demonstrates that strong light–matter coupling between vibrational excitations in isotropic solutions of molecules and resonant infrared optical microcavity modes leads to modified thermally activated kinetics. However, Galego et al.[Phys. Rev. X 9, 021057 (2019)] recently demonstrated that, within transition state theory, effects of strong light–matter coupling with reactive modes are mostly electrostatic and essentially independent of light–matter resonance or even of the formation of vibrational polaritons. To analyze this puzzling theoretical result in further detail, we revisit it under a new light, invoking a normal mode analysis of the transition state and reactant configurations for an ensemble of an arbitrary number of molecules in a cavity, obtaining simple analytical expressions that produce similar conclusions as Feist. While these effects become relevant in optical microcavities if the molecular …
Total citations
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Scholar articles
JA Campos-Gonzalez-Angulo, J Yuen-Zhou - The Journal of chemical physics, 2020