Authors
Matthew Du, Luis A Martínez-Martínez, Raphael F Ribeiro, Zixuan Hu, Vinod M Menon, Joel Yuen-Zhou
Publication date
2018
Journal
Chemical science
Volume
9
Issue
32
Pages
6659-6669
Publisher
Royal Society of Chemistry
Description
Strong-coupling between light and matter produces hybridized states (polaritons) whose delocalization and electromagnetic character allow for novel modifications in spectroscopy and chemical reactivity of molecular systems. Recent experiments have demonstrated remarkable distance-independent long-range energy transfer between molecules strongly coupled to optical microcavity modes. To shed light on the mechanism of this phenomenon, we present the first comprehensive theory of polariton-assisted remote energy transfer (PARET) based on strong-coupling of donor and/or acceptor chromophores to surface plasmons. Application of our theory demonstrates that PARET up to a micron is indeed possible. In particular, we report two regimes for PARET: in one case, strong-coupling to a single type of chromophore leads to transfer mediated largely by surface plasmons while in the other case, strong-coupling …
Total citations
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Scholar articles
M Du, LA Martínez-Martínez, RF Ribeiro, Z Hu… - Chemical science, 2018