Authors
Luis A Martínez-Martínez, Matthew Du, Raphael F Ribeiro, Stéphane Kéna-Cohen, Joel Yuen-Zhou
Publication date
2018/3/18
Journal
The Journal of Physical Chemistry Letters
Volume
9
Issue
8
Pages
1951-1957
Publisher
American Chemical Society
Description
Singlet fission is an important candidate to increase energy conversion efficiency in organic photovoltaics by providing a pathway to increase the quantum yield of excitons per photon absorbed in select materials. We investigate the dependence of exciton quantum yield for acenes in the strong light-matter interaction (polariton) regime, where the materials are embedded in optical microcavities. Starting from an open-quantum-systems approach, we build a kinetic model for time-evolution of species of interest in the presence of singlet quenchers and show that polaritons can decrease or increase exciton quantum yields compared to the cavity-free case. In particular, we find that hexacene, under the conditions of our model, can feature a higher yield than cavity-free pentacene when assisted by polaritonic effects. Similarly, we show that pentacene yield can be increased when assisted by polariton states. Finally, we …
Total citations
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Scholar articles
LA Martínez-Martínez, M Du, RF Ribeiro… - The Journal of Physical Chemistry Letters, 2018