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Assisted ruthenium-catalyzed C− H bond activation: carboxylic acids as cocatalysts for generally applicable direct arylations in apolar solvents

Authors

Lutz Ackermann, Ruben Vicente, Andreas Althammer

Publication date

2008/6/5

Journal

Organic Letters

Volume

Issue

Pages

2299-2302

Publisher

American Chemical Society

Description

Catalytic amounts of aromatic carboxylic acid MesCO₂H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation−metalation mechanism.

Total citations

Cited by 444

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Assisted ruthenium-catalyzed C− H bond activation: carboxylic acids as cocatalysts for generally applicable direct arylations in apolar solvents

L Ackermann, R Vicente, A Althammer - Organic Letters, 2008