Authors
Seth S Berbano, Jing Guo, Hanzheng Guo, Michael T Lanagan, Clive A Randall
Publication date
2017/5/1
Journal
Journal of the American Ceramic Society
Volume
100
Issue
5
Pages
2123-2135
Description
The recently developed technique of cold sintering process (CSP) enables densification of ceramics at low temperatures, i.e., <300°C. CSP employs a transient aqueous solvent to enable liquid phase‐assisted densification through mediating the dissolution‐precipitation process under a uniaxial applied pressure. Using CSP in this study, 80% dense Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolytes were obtained at 120°C in 20 minutes. After a 5 minute belt furnace treatment at 650°C, 50°C above the crystallization onset, Li‐ion conductivity was 5.4 × 10−5 S/cm at 25°C. Another route to high ionic conductivities ~10−4 S/cm at 25°C is through a composite LAGP ‐ (PVDF‐HFP) co‐sintered system that was soaked in a liquid electrolyte. After soaking 95, 90, 80, 70, and 60 vol% LAGP in 1 M LiPF6 EC‐DMC (50:50 vol%) at 25°C, Li‐ion conductivities were 1.0 × 10−4 S/cm at 25°C with 5 to 10 wt% liquid electrolyte. This …
Total citations
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Scholar articles
SS Berbano, J Guo, H Guo, MT Lanagan, CA Randall - Journal of the American Ceramic Society, 2017