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Typically, commercial Mn-Zn ferrites are sintered at high temperatures with prolong times. In this work, commercial Fe₂O₃-rich ferrite powders with the composition of 0.21Mn_0.8Zn_0.2Fe₂O₄-0.79Fe₂O₃ (wt%) are densified by cold sintering at 300 °C with the assistance of organic salts, including MnC₂O₄·2H₂O, FeC₂O₄·2H₂O, and Zn(C₂H₃O₂)₂·2H₂O. Excessive Fe₂O₃ enters into spinel structure forming a solid solution through annealing in low pO₂ at 1350 °C. The sintering behaviors, microstructures, magnetic properties and impedances are investigated. The dehydration of organic salts provides mediate liquid phase to trigger the dissolution-precipitation process, which assists the densification of ceramics. The grains grow from 0.15 µm to 0.52 µm and 7.67 µm after cold sintering at 300 °C and annealing at 1350 °C, respectively. The initial permeability of cold sintered sample is improved to 11000 with a Curie …