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Recently discovered^, valley photonic crystals (VPCs) mimic many of the unusual properties of two-dimensional (2D) gapped valleytronic materials^,,,,,,. Of the utmost interest to optical communications is their ability to support topologically protected chiral edge (kink) states^,,,,,, at the internal domain wall between two VPCs with opposite valley-Chern indices. Here we experimentally demonstrate valley-polarized kink states with polarization multiplexing in VPCs, designed from a spin-compatible four-band model. When the valley pseudospin is conserved, we show that the kink states exhibit nearly perfect out-coupling efficiency into directional beams, through the intersection between the internal domain wall and the external edge separating the VPCs from ambient space. The out-coupling behaviour remains topologically protected even when we break the spin-like polarization degree of freedom (DOF), by introducing …