Authors
Mehdi M Yazdanpanah, Mahdi Hosseini, Santosh Pabba, Scott M Berry, Vladimir V Dobrokhotov, Abdelilah Safir, Robert S Keynton, Robert W Cohn
Publication date
2008/12/2
Journal
langmuir
Volume
24
Issue
23
Pages
13753-13764
Publisher
American Chemical Society
Description
The micro-Wilhelmy method is a well-established method of determining surface tension by measuring the force of withdrawing a tens of microns to millimeters in diameter cylindrical wire or fiber from a liquid. A comparison of insertion force to retraction force can also be used to determine the contact angle with the fiber. Given the limited availability of atomic force microscope (AFM) probes that have long constant diameter tips, force−distance (FD) curves using probes with standard tapered tips have been difficult to relate to surface tension. In this report, constant diameter metal alloy nanowires (referred to as “nanoneedles”) between 7.2 and 67 μm in length and 108 and 1006 nm in diameter were grown on AFM probes. FD and Q damping AFM measurements of wetting and drag forces made with the probes were compared against standard macroscopic models of these forces on slender cylinders to estimate …
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