Authors
Andrew Beeby, Sylvia Bettington, Ian JS Fairlamb, Andrés E Goeta, Anant R Kapdi, Elina H Niemelä, Amber L Thompson
Publication date
2004
Journal
New Journal of Chemistry
Volume
28
Issue
5
Pages
600-605
Publisher
Royal Society of Chemistry
Description
A dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(μ-C5H4N-C2,N)(PPh3)]21, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-difluorophenylboronic acid in the presence of catalytic (PPh3)4Pd. Complex 1 is an effective precatalyst for the Suzuki cross-coupling reactions of a variety organoboronic acids and aryl bromides, and represents a useful source of mono-ligated palladium(0), “(Ph3P)Pd(0)”.
Total citations
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Scholar articles
A Beeby, S Bettington, IJS Fairlamb, AE Goeta… - New Journal of Chemistry, 2004