Authors
Mikhail Meilikhov, Kirill Yusenko, Daniel Esken, Stuart Turner, Gustaaf Van Tendeloo, Roland A Fischer
Publication date
2010/8
Source
European Journal of Inorganic Chemistry
Volume
2010
Issue
24
Pages
3701-3714
Publisher
WILEY‐VCH Verlag
Description
Metal–organic frameworks (MOFs) as well as porous coordination polymers (PCPs) are porous, organic–inorganic hybrid solids with zeolite‐like structures and properties. Due to their extraordinarily high surface area and well defined pore structure MOFs can be used for the stabilization of metal nanoparticles with adjustable size. The embedded metal nanoparticles are still accessible for other reagents due to the high porosity of the MOF systems. This fact makes “metal@MOF” systems especially interesting for heterogeneous catalysis, gas storage and chemical sensing. This review compiles the cases of metal nanoparticles supported by or embedded into MOFs reported so far and the main aspects and problems associated with these novel nanocomposite systems. The determination of the dispersion and the location of the particles at the MOF support, the control of the loading degree and its effect on the …
Total citations
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Scholar articles
M Meilikhov, K Yusenko, D Esken, S Turner… - European Journal of Inorganic Chemistry, 2010