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The electron and hole multiplication coefficients, M/sub e/ and M/sub h/, respectively, have been measured in thin GaAs homojunction PIN and NIP diodes and from conventional ionization analysis the effective electron and hole ionization coefficients, /spl alpha/ and /spl beta/, respectively, have been determined. The nominal intrinsic region thickness w of these structures ranges from 1.0 /spl mu/m down to 25 nm. In the thicker structures, bulk-like behavior is observed; however, in the thinner structures, significant differences are found. As the i-regions become thinner and the electric fields increase, the M/sub e//M/sub h/ ratio is seen to approach unity. The experimental results are modeled and interpreted using a semianalytical solution of the Boltzmann equation. In thin (w/spl les/0.1 /spl mu/m) devices the dead space effect reduces effective ionization coefficients below their bulk values at low values of carrier …