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The magnesium–sulfur (MgS) battery is a promising alternative to the post-lithium battery because of its low-cost construction, eco-friendliness, high theoretical energy density, and safety. However, the lack of simple compatible electrolytes, self-discharge, polysulfide shuttle effect, and the slow conversion reaction pathway still limit its practical applications. Here, we propose a simple halogen-free electrolyte (HFE) based on Mg(NO₃)₂ dissolved in the cosolvent of acetonitrile (ACN) and tetraethylene glycol dimethyl (G4) that applies to a Mg/S full cell. The as-prepared Mg-ion electrolyte exhibits efficient Mg plating/stripping performance, high anodic stability (vs Mg/Mg²⁺), and a high ionic conductivity of ∼10^–4 S cm^–1 at 313 K. Chronoamperometry (CA), scanning electron microscopy, and energy-dispersive spectroscopy examinations report that the HFE supports flat, dendrite-free, and translucent Mg deposits …