Authors
Stephanie Flude, Gareth Johnson, Stuart MV Gilfillan, R Stuart Haszeldine
Publication date
2016/8/2
Source
Environmental Science & Technology
Volume
50
Issue
15
Pages
7939-7955
Publisher
American Chemical Society
Description
Inherent tracersthe “natural” isotopic and trace gas composition of captured CO2 streamsare potentially powerful tracers for use in CCS technology. This review outlines for the first time the expected carbon isotope and noble gas compositions of captured CO2 streams from a range of feedstocks, CO2-generating processes, and carbon capture techniques. The C-isotope composition of captured CO2 will be most strongly controlled by the feedstock, but significant isotope fractionation is possible during capture; noble gas concentrations will be controlled by the capture technique employed. Comparison with likely baseline data suggests that CO2 generated from fossil fuel feedstocks will often have δ13C distinguishable from storage reservoir CO2. Noble gases in amine-captured CO2 streams are likely to be low concentration, with isotopic ratios dependent on the feedstock, but CO2 captured from oxyfuel plants …
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