Authors
Marco Califano, Alberto Franceschetti, Alex Zunger
Publication date
2007/3/15
Journal
Physical Review B—Condensed Matter and Materials Physics
Volume
75
Issue
11
Pages
115401
Publisher
American Physical Society
Description
Using the pseudopotential configuration-interaction method, we calculate the intrinsic lifetime and polarization of the radiative decay of single excitons , positive and negative trions ( and ), and biexcitons in CdSe nanocrystal quantum dots. We investigate the effects of the inclusion of increasingly more complex many-body treatments, starting from the single-particle approach and culminating with the configuration-interaction scheme. Our configuration-interaction results for the size dependence of the single-exciton radiative lifetime at room temperature are in excellent agreement with recent experimental data. We also find the following. (i) Whereas the polarization of the bright exciton emission is always perpendicular to the hexagonal axis, the polarization of the dark exciton switches from perpendicular to parallel to the hexagonal axis in large dots, in agreement with experiment. (ii) The ratio of the radiative lifetimes of …
Total citations
20062007200820092010201120122013201420152016201720182019202020212022202320241989610101212812119159692
Scholar articles