Authors
RR Chance, A Prock, R Silbey
Publication date
1974/4/1
Journal
The Journal of Chemical Physics
Volume
60
Issue
7
Pages
2744-2748
Publisher
American Institute of Physics
Description
A classical treatment of energy transfer in metal insulator systems is presented. The approach involves the calculation of the radiation field of an emitting molecule near a partially reflecting surface. The modification of the image theory result produces a large correction when the molecule is near the surface. This in turn produces a correction to the calculated lifetime of the molecule as a function of distance from the surface that differs substantially from previous theoretical descriptions of this system and brings the theory into good agreement with experiment.
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