作者
Zhihui Ye, Dong Chen, Zhejun Pan, Guangqing Zhang, Yang Xia, Xiang Ding
发表日期
2016/4/1
期刊
Journal of Natural Gas Science and Engineering
卷号
31
页码范围
658-680
出版商
Elsevier
简介
A large amount of experimental data for methane adsorption capacity in shale are available and the Langmuir model is capable to describe most of these adsorption isotherms. Two parameters used in the Langmuir model are the Langmuir pressure constant PL and the Langmuir volume constant VL. However, experimental data also demonstrate that the gas adsorption capacity of shale is greatly affected by temperature and the classic Langmuir model, with temperature independent VL and temperature dependent PL, could not well interpret the experimental data. This is partly attributed to the isosteric heat of adsorption, which makes VL vary with temperature. The change of VL with temperature for gas adsorption in shale and its dependency on shale properties are still not well understood. In this study, the variation characteristics of VL with temperature for gas shale are investigated through a modeling analysis …
引用总数
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