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The Valle del Bove is a profound and wide scar on the east Etna flank witnessing the Holocene main volcano-tectonic event of the volcano, frequently invaded by lava flows during the last centuries. The Valle del Bove slope failure produced the Milo debris avalanche deposit on the lower east flank that is partially covered by the Mongibello lavas and a pyroclastic succession. In this paper, we constrain for the first time the age of the Milo debris avalanche deposit and the overlying lava succession exposed at three quarries recently caved at the valley mouth through a multidisciplinary approach integrating stratigraphic and petrographic analyses, ¹⁴C, and paleomagnetic dating. In particular, ¹⁴C age determinations of the Milo debris avalanche deposit indicate that the initial stage of the catastrophic flank collapse of the Valle del Bove occurred at 7478–7134 BCE during the Mesolithic age. Conversely, the main …