Authors
Ilya Rips
Publication date
1993/1/1
Journal
Physical Review E
Volume
47
Issue
1
Pages
67-79
Publisher
American Physical Society
Description
Exciton dephasing in crystals due to the phonon scattering is studied within the framework of the stochastic Haken-Strobl model. The model corresponds to the extremely fast-modulation limit and is applicable to triplet excitons in molecular crystals. The model describes the crossover from the coherent (band) short-time exciton dynamics to incoherent diffusive motion on the long time scale. An efficient method for the determination of the moments of the exciton displacement is developed. Analytic expressions for the mean-square displacement tensor and for the fourth-order moment of exciton displacement on a three-dimensional lattice with inversion symmetry are derived. Solution of the model for arbitrary initial conditions is obtained. The equilibrium state of the system corresponds to the uniform population of the states in the exciton band. The equilibration time scale coincides with the time scale on which the …
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