Authors
Daniel Streich, Yeni Astuti, Michele Orlandi, Lennart Schwartz, Reiner Lomoth, Leif Hammarström, Sascha Ott
Publication date
2009/12/23
Journal
Chemistry–A European Journal
Volume
1
Issue
16
Pages
60-63
Description
Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light‐driven proton reduction process in near‐neutral H2O/DMF (pH 5.5) by using an [FeFe]‐hydrogenase active‐site model complex as the catalyst (see scheme).
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D Streich, Y Astuti, M Orlandi, L Schwartz, R Lomoth… - Chemistry–A European Journal, 2009