Authors
Edward D Burton, Richard T Bush, Scott G Johnston, Leigh A Sullivan, Annabelle F Keene
Publication date
2011/6/15
Journal
Geochimica et Cosmochimica Acta
Volume
75
Issue
12
Pages
3434-3451
Publisher
Pergamon
Description
Sulfur biogeochemical cycling and associated Fe–S mineralization processes exert a major influence over acidity dynamics, electron flow and contaminant mobility in wetlands, benthic sediments and groundwater systems. While S biogeochemical cycling has been studied intensively in many environmental settings, relatively little direct information exists on S cycling in formerly drained wetlands that have been remediated via tidal re-flooding. This study focuses on a tidal wetland that was drained in the 1970s (causing severe soil and water acidification), and subsequently remediated by controlled re-flooding in 2002. We examine SO 4 2-reduction rates and Fe–S mineralization at the tidal fringe, 7 years after the commencement of re-flooding. The initial drainage of the wetland examined here caused in-situ pyrite (FeS 2) oxidation, resulting in the drained soil layers being highly acidic and rich in SO 4 2--bearing Fe …
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