Authors
Scott G Johnston, Edward D Burton, Thor Aaso, Gerard Tuckerman
Publication date
2014/4/15
Journal
Chemical geology
Volume
371
Pages
9-26
Publisher
Elsevier
Description
Freshwater re-flooding is a relatively novel approach to remediate drained acid sulfate soil (ASS) wetlands. This study documents the geochemical consequences of restoring freshwater re-flooding for contemporary reduced inorganic sulfur (RIS) and iron species in two coastal floodplain ASS wetlands. Re-flooding has established predominantly reducing/suboxic conditions and encouraged organic carbon accumulation in surface sediments (~ 20–30%). The pH of former sulfuric horizons has increased by ~ 2–3 units, partly in response to alkalinity generation from anaerobic metabolism of organic carbon coupled with Fe(III) and SO42 − reduction. Despite considerable sulfidisation, reactive Fe (FeR; sum of 1 M HCl and citrate–dithionite extracts) and non-sulfidic Fe(II) remain abundant in both wetlands. High concentrations of Fe2 + (up to ~ 5 mM) in wetland porewaters represent a considerable pool of labile net …
Total citations
20142015201620172018201920202021202220232024191298181817101111