Authors
Ragip A Pala, Justin White, Edward Barnard, John Liu, Mark L Brongersma
Publication date
2009/9/11
Journal
Adv. Mater
Volume
21
Issue
34
Pages
3504-3509
Description
Basic design rules are developed for the use of metallic nanostructures to realize broadband absorption enhancements in thin-film solar cells. They are applied to a relevant and physically intuitive model system consisting of a two-dimensional, periodic array of Ag strips on a silica-coated Si film supported by a silica substrate. We illustrate how one can simultaneously take advantage of 1) the high near-fields surrounding the nanostructures close to their surface plasmon resonance frequency and 2) the effective coupling to waveguide modes supported by the thin Si film through an optimization of the array properties. Following this approach, we can attain a 43% enhancement in the short circuit current as compared to a cell without metallic structures. It is suggested that 3-dimensional nanoparticle arrays with even larger boosts in short circuit current can also be generated using the presented framework. Photovoltaic (PV) cells can provide virtually unlimited amounts of energy by effectively converting sunlight into clean electrical power. Silicon has been the material of choice for PV cells due to low cost, earth abundance, non-toxicity, and the availability of a very mature processing technology. The cost of current PV modules still needs to be significantly reduced and efficiency substantially increased to enable large scale implementation. Thin-film, second-generation Si solar cells may provide a viable pathway towards this goal because of their low materials and processing costs.[1] Unfortunately the materials quality and resulting energy conversion efficiencies of such cells are still substantially lower than crystalline, wafer-based cells. This is a …
Total citations
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