Authors
Andrew P Grieshop, Marissa A Miracolo, Neil M Donahue, Allen L Robinson
Publication date
2009/7/1
Journal
Environmental science & technology
Volume
43
Issue
13
Pages
4750-4756
Publisher
American Chemical Society
Description
The gas-particle partitioning of primary organic aerosol (POA) emissions from a diesel engine and the combustion of hard- and soft-woods in a stove was investigated by isothermally diluting them in a smog chamber or by passing them through a thermodenuder and measuring the extent of evaporation. The experiments were conducted at atmospherically relevant conditions: low concentrations and small temperature perturbations. The partitioning of the POA emissions from both sources varied continuously with changing concentration and temperature. Although the POA emissions are semivolatile, they do not completely evaporate at typical atmospheric conditions. The overall partitioning characteristics of diesel and wood smoke POA are similar, with wood smoke being somewhat less volatile than the diesel exhaust. The gas-particle partitioning of aerosols formed from flash-vaporized engine lubricating oil was …
Total citations
20092010201120122013201420152016201720182019202020212022202320246881016613911976210105