Authors
Julian A Steele, Handong Jin, Iurii Dovgaliuk, Robert F Berger, Tom Braeckevelt, Haifeng Yuan, Cristina Martin, Eduardo Solano, Kurt Lejaeghere, Sven MJ Rogge, Charlotte Notebaert, Wouter Vandezande, Kris PF Janssen, Bart Goderis, Elke Debroye, Ya-Kun Wang, Yitong Dong, Dongxin Ma, Makhsud Saidaminov, Hairen Tan, Zhenghong Lu, Vadim Dyadkin, Dmitry Chernyshov, Veronique Van Speybroeck, Edward H Sargent, Johan Hofkens, Maarten BJ Roeffaers
Publication date
2019/8/16
Journal
Science
Volume
365
Issue
6454
Pages
679-684
Publisher
American Association for the Advancement of Science
Description
The high-temperature, all-inorganic CsPbI3 perovskite black phase is metastable relative to its yellow, nonperovskite phase at room temperature. Because only the black phase is optically active, this represents an impediment for the use of CsPbI3 in optoelectronic devices. We report the use of substrate clamping and biaxial strain to render black-phase CsPbI3 thin films stable at room temperature. We used synchrotron-based, grazing incidence, wide-angle x-ray scattering to track the introduction of crystal distortions and strain-driven texture formation within black CsPbI3 thin films when they were cooled after annealing at 330°C. The thermal stability of black CsPbI3 thin films is vastly improved by the strained interface, a response verified by ab initio thermodynamic modeling.
Total citations
201920202021202220232024138911711110488
Scholar articles
JA Steele, H Jin, I Dovgaliuk, RF Berger, T Braeckevelt… - Science, 2019