Authors
Jean MJ Frechet, Eva Eichler, Hiroshi Ito, C Grant Willson
Publication date
1983/8/1
Journal
Polymer
Volume
24
Issue
8
Pages
995-1000
Publisher
Elsevier
Description
An efficient synthetic route to pure, high molecular weight poly(p-hydroxystyrene) is reported. The route involves synthesis of a new monomer, p-tert-butoxycarbonyloxystyrene, polymerization by radical initiation or by cationic initiation in liquid SO2, followed by thermolysis or acidolysis of the tert-butoxycarbonyl protecting group. Porous, crosslinked resin beads containing the nucleophilic, phenol pendant group have been prepared in a similar fashion from the precursor terpolymer of p-tert-butoxycarbonyloxystyrene, styrene and divinylbenzene. The utility of this resin for solid-phase synthesis has been demonstrated.
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Scholar articles
JMJ Frechet, E Eichler, H Ito, CG Willson - Polymer, 1983