Authors
Quinten A Akkerman, Silvia Genaro Motti, Ajay Ram Srimath Kandada, Edoardo Mosconi, Valerio D’Innocenzo, Giovanni Bertoni, Sergio Marras, Brett A Kamino, Laura Miranda, Filippo De Angelis, Annamaria Petrozza, Mirko Prato, Liberato Manna
Publication date
2016/1/27
Journal
Journal of the American Chemical Society
Volume
138
Issue
3
Pages
1010-1016
Publisher
American Chemical Society
Description
We report a colloidal synthesis approach to CsPbBr3 nanoplatelets (NPLs). The nucleation and growth of the platelets, which takes place at room temperature, is triggered by the injection of acetone in a mixture of precursors that would remain unreactive otherwise. The low growth temperature enables the control of the plate thickness, which can be precisely tuned from 3 to 5 monolayers. The strong two-dimensional confinement of the carriers at such small vertical sizes is responsible for a narrow PL, strong excitonic absorption, and a blue shift of the optical band gap by more than 0.47 eV compared to that of bulk CsPbBr3. We also show that the composition of the NPLs can be varied all the way to CsPbBr3 or CsPbI3 by anion exchange, with preservation of the size and shape of the starting particles. The blue fluorescent CsPbCl3 NPLs represent a new member of the scarcely populated group of blue-emitting …
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