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Coprecipitation synthesis methods followed by microwave sintering techniques were utilized to obtain dense phase pure Bi₂Ti₂O₇ polycrystalline ceramic pellets. No evidence of secondary phases was found in the powder or pellets. This maiden achievement allowed for primary thermophysical, crystallographic, and dielectric characterization of this ceramic compound. Density functional theory was used to model the structure of the pyrochlore, from which the theoretical X-ray diffraction pattern was obtained to determine the purity of the experimental compound. Discrepancies among reports in literature regarding the structure, stability, and supposed ferroelectricity of this material are discussed and clarified. A modification to the phase diagram of the Bi₂O₃–TiO₂ system is proposed based on the results of the present investigation. In addition, and contrary to prior reports, the dielectric characterization of Bi₂Ti₂O₇ …