Authors
Evangelia Demou, DJ Donaldson
Publication date
2002/2/14
Journal
The Journal of Physical Chemistry A
Volume
106
Issue
6
Pages
982-987
Publisher
American Chemical Society
Description
We have measured the standard free energies and standard enthalpies of adsorption as well as saturated surface coverages for hexanoic acid and 1-propanol adsorbed at the air−aqueous interface of sodium chloride (NaCl) and ammonium sulfate ((NH4)2SO4) solutions of concentrations between 0 and 4 mol L-1. Temperature-dependent surface tension measurements are used to obtain ΔG0aq→σ and ΔH0aq→σ; using known Henry's law constants and estimated values of the salting-out coefficient we calculate the gas−interface adsorption parameters ΔG0g→σ and ΔH0g→σ. A small (∼1−2 kJ mol-1) decrease in ΔG0aq→σ with increasing salt concentration is accompanied by an increase (∼10−30%) in saturated surface coverage, consistent with the expected “salting-out” behavior. Adsorption from the gas phase becomes somewhat less favorable with increasing salt concentration for both organic species. The …
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Scholar articles
E Demou, DJ Donaldson - The Journal of Physical Chemistry A, 2002