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Anodic oxidation has emerged as a promising treatment technology for the removal of a broad range of organic pollutants from wastewaters. Hydroxyl radicals are the primary species generated in anodic oxidation systems to oxidize organics. In this review, the methods of identifying hydroxyl radicals and the existing debates and misunderstandings regarding the validity of experimental results are discussed. Consideration is given to the methods of quantification of hydroxyl radicals in anodic oxidation systems with particular attention to approaches used to compare the electrochemical performance of different anodes. In addition, we describe recent progress in understanding the mechanisms of hydroxyl radical generation at the surface of most commonly used anodes and the utilization of hydroxyl radical in typical electrochemical reactors. This review shows that the key challenges facing anodic oxidation …