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Computation of metal temperatures in a furnace waterwall of a boiler is necessary for the proper selection of tube material and thickness. An adequate knowledge of the heat flux distribution in the furnace walls is a prerequisite for the computation of metal temperatures. Hence, the measurement of heat flux in a boiler waterwall is necessary to arrive at an optimum furnace design, especially for high ash Indian coal fired boilers. Also, a thoroughly validated furnace model will result in a considerable reduction of the quantum of experimentation to be carried out. In view of the above mentioned scenario, this paper reviews the research work carried out by various researchers by experimentation and numerical simulation in the below mentioned areas: (i) furnace modeling and heat flux prediction, (ii) heat flux measurement techniques and (iii) applications of heat flux measurements.