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One major advantage of organic electronics is their superior processability relative to traditional silicon-based materials. However, most high-performing polymer semiconductors exhibit poor solubility and require toxic chlorinated solvents coupled with inefficient coating methods such as spin-coating for device fabrication. Therefore, developing polymer semiconductors that are processable in environmentally benign solvents and compatible with effective printing techniques while maintaining good charge transport properties is crucial for the industrialization of low-cost and lightweight plastic electronics. In this study, alkyl flexible linkers with branched tertiary carbon atoms are inserted to a high-mobility diketopyrrolopyrrole-based polymer backbone to suppress polymer aggregation in solution, decrease crystallinity, and increase free volume. The polymer readily dissolves in industrial solvents and shows a 70-fold …