Authors
Nan Li, Yahao Dai, Yang Li, Shilei Dai, Joseph Strzalka, Qi Su, Nickolas De Oliveira, Qingteng Zhang, P Blake J St Onge, Simon Rondeau-Gagné, Yunfei Wang, Xiaodan Gu, Jie Xu, Sihong Wang
Publication date
2021/9/1
Journal
Matter
Volume
4
Issue
9
Pages
3015-3029
Publisher
Elsevier
Description
Polymer semiconductors have shown distinct promise for the development of human-integrated electronics, owing to their solution processability and mechanical softness. However, numerous functional properties required for this application domain face synthetic challenges to being conveyed onto conjugated polymers and thus combined with efficient charge-transport properties. Here, we develop a "click-to-polymer" (CLIP) synthesis strategy for conjugated polymers, which uses a click reaction for the facile and versatile attachment of diverse types of functional units to a pre-synthesized conjugated-polymer precursor. With four types of functional groups, we show that functionalized polymers from this CLIP method can still retain good charge-carrier mobility. We take two realized polymers to showcase a photopatternable property and a biochemical sensing function, both of which advance the state of the art of …
Total citations
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