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Aimed at the analysis of hydrogen bond interactions, the molecular structure of biphenyl-2, 2ÔÇ▓-dimethanol (C14H14O2) has been determined by X-ray crystallographic techniques. The compound crystallizes in the monoclinic space group P21/n with unit cell parameters: a =12.811(4)┬á├à, b=5.009(4)┬á├à, c=18.591(14)┬á├à, and ╬▓=109.24(5)┬░, Z=4, V=1126.3(13)┬á├à3. The magnitude of the interring torsion angle is 87.5┬░. There are OÔÇôH Formula Not Shown O and CÔÇôH Formula Not Shown ¤Ç interactions which leads the structure to architectural supramolecular synthon.