Authors
Mahmoud Shams, Mohammad Hadi Dehghani, Ramin Nabizadeh, Alireza Mesdaghinia, Mahmood Alimohammadi, Ali Asghar Najafpoor
Publication date
2016/12/1
Journal
Journal of Molecular Liquids
Volume
224
Pages
151-157
Publisher
Elsevier
Description
Cubic zeolitic imidazolate framework-8 (ZIF-8), a new class of hybrid adsorbent, was synthesized and investigated for phosphorus (P) removal from aqueous solution. A prediction model for P adsorption was developed by performing the experiments according to central composite design. The adsorption model showed that P adsorption is associated directly with time and ZIF-8 dosage and indirectly with initial P concentration. The removal also increased with decrease in pH until reaching the critical pH of about 2.6. The efficiency of P removal under mechanically stirred increased with agitation speed from 100 to 300 rpm. In contrast to high ultrasonic frequency (130 kHz), sonication under 35 kHz provides excellent dispersive mixing and shortened the equilibrium time. Study of coexisting ions showed that P adsorption hindered considerably in the presence of carbonate. Equilibrium studies indicated that P adsorbed …
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