Authors
Daniel Graeber, Gulliermo Goyenola, Mariana Meerhoff, Elke Zwirnmann, Niels B Ovesen, Miriam Glendell, Jörg Gelbrecht, F Teixeira de Mello, Ivan González-Bergonzoni, Erik Jeppesen, Brian Kronvang
Publication date
2015/5/20
Journal
Hydrology and Earth System Sciences
Volume
19
Issue
5
Pages
2377-2394
Publisher
Copernicus GmbH
Description
Dissolved organic matter (DOM) is an important factor in aquatic ecosystems, which is involved in a large variety of biogeochemical and ecological processes, and recent literature suggests that it could be strongly affected by agriculture in different climates. Based on novel monitoring techniques, we investigated the interaction of climate and agriculture effects on DOM quantity and quality. To examine this, we took water samples over 2 years in two paired intensive and extensive farming catchments in each of Denmark (temperate climate) and Uruguay (subtropical climate). We measured dissolved organic carbon (DOC) and nitrogen (DON) concentrations and DOC and DON molecular fractions with size-exclusion chromatography. Moreover, we characterized DOM quality with absorbance and fluorescence measurements, as well as parallel factor analysis (PARAFAC). We also calculated the DOC and DON loads based on daily discharge measurements, as well as measured precipitation and air temperature. The fluvial DOM in the catchments in Uruguay was characterized by higher temporal variability of DOC and DON loads which were clearly to a higher temporal variability of precipitation and a DOM composition with rather plant-like character relative to the Danish catchments. Moreover, we found a consistently higher temporal variability of DOC and DON loads in the intensive farming catchments than in the extensive farming catchments, with highest temporal variability in the Uruguayan intensive farming catchment. Furthermore, the composition of DOM exported from the intensive farming catchments was consistently complex and always …
Total citations
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Scholar articles
D Graeber, G Goyenola, M Meerhoff, E Zwirnmann… - Hydrology and Earth System Sciences, 2015