Authors
Kyungho Lee, Mi-Eun Lee, Jae-Kon Kim, Byeongcheol Shin, Minkee Choi
Publication date
2019/11/1
Journal
Journal of Catalysis
Volume
379
Pages
180-190
Publisher
Academic Press
Description
The direct hydroconversion of triglycerides into biojet fuel (i.e., cascade reactions including hydrogenation, deoxygenation, and hydrocracking) is challenging, even though it is beneficial in terms of process intensification. This is because the minute amount of CO produced during deoxygenation can poison the metal component of various metal–acid bifunctional catalysts, causing undesired overcracking and rapid catalyst deactivation through coke formation. To overcome this problem, we synthesized a CO-tolerant catalyst by supporting bimetallic PtRe on ultra-stable Y (USY) zeolite as acidic support. Compared to conventional catalyst (e.g., Pt/USY), PtRe/USY showed markedly enhanced tolerance to CO because it had weakened interaction with CO and also could rapidly convert the chemisorbed CO into less harmful methane and H2O through methanation. Consequently, overcracking and catalyst deactivation …
Total citations
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