Authors
Qi Yang, Guojin Liang, Ying Guo, Zhuoxin Liu, Boxun Yan, Donghong Wang, Zhaodong Huang, Xinliang Li, Jun Fan, Chunyi Zhi
Publication date
2019/10
Journal
Advanced materials
Volume
31
Issue
43
Pages
1903778
Description
The dendritic issue in aqueous zinc‐ion batteries (ZBs) using neutral/mild electrolytes has remained an intensive controversy for a long time: some researchers assert that dendrites severely exist while others claim great cycling stability without any protection. This issue is clarified by investigating charge/discharge‐condition‐dependent formation of Zn dendrites. Lifespan degradation (120 to 1.2 h) and voltage hysteresis deterioration (134 to 380 mV) are observed with increased current densities due to the formation of Zn dendrites (edge size: 0.69–4.37 µm). In addition, the capacity is also found to remarkably affect the appearance of the dendrites as well. Therefore, at small current densities or loading mass, Zn dendrites might not be an issue, while the large conditions may rapidly ruin batteries. Based on this discovery, a first‐in‐class electrohealing methodology is developed to eliminate already‐formed dendrites …
Total citations
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